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Why you should not laser PVC

PVC contains chloride, which is a negatively charged ion (anion). When heated by the laser, chloride becomes a toxic gas that actively seeks positive particles to reach a balanced state. This chemical reaction causes severe damage to both your machine and your health.

PVC is not the only dangerous material. Avoid processing any materials containing these anions:

  • Fluoride (F-) - Found in fluoropolymers and some plastics
  • Bromide (Br-) - Found in flame retardants and some vinyl compounds
  • Iodide (I-) - Found in certain chemical compounds
  • Chloride (Cl-) - Found in PVC, vinyl, and chlorinated plastics

When you laser PVC or chloride-containing materials, the released gas doesn’t just disappear—it actively attacks everything it touches.

The chloride gas pulls positive particles from metal components to balance itself. This process:

  • Corrodes steel parts - Components appear rusty and turn orange
  • Damages moving parts - Motors, bearings, and guide wheels deteriorate
  • Creates mechanical play - The laser head and axes become loose and inaccurate
  • Destroys precision - Your machine loses accuracy and eventually stops working

The images below show typical damage from chloride exposure:

Corroded mirror mount and belt holder

Damaged motor and guide wheel

Chloride gas is toxic to humans. Even with extraction systems, you cannot safely remove these gases. The health effects are severe and include:

  • Immediate effects: Eye irritation, burning sensation, respiratory discomfort
  • Short-term exposure: Lung damage, skin irritation
  • Long-term exposure: Potential blindness, permanent lung damage, increased cancer risk

Unfortunately, accidental exposure causes permanent damage. The corrosion process continues until all anions reach chemical balance, which can take months after the initial exposure.

Unlike rust (which is self-sustaining), anions stop causing damage once they reach balance. However, you cannot predict when this will happen. The gas particles settle throughout your machine and continue corroding new surfaces they contact.

Replacing individual parts is difficult because:

  1. Chloride particles accumulate throughout the machine
  2. New parts immediately contact contaminated surfaces
  3. The corrosion process transfers to replacement parts
  4. It’s impossible to know when all anions have balanced

If you must attempt repairs, follow this decontamination process carefully.

  1. Wipe down all surfaces with damp cloths

    • Remove every trace of dust and residue
    • Pay special attention to corners, crevices, and hidden areas
    • The machine must be completely dust-free
  2. Do NOT use vacuum cleaners or compressed air

    • Vacuums lack appropriate filters and will spread anions throughout your workspace
    • Compressed air simply displaces the problem
    • The vacuum cleaner itself will become contaminated and fail
  3. Dispose of cleaning materials properly

    • Treat all cloths as chemical waste
    • Follow local hazardous waste disposal regulations
  4. Wait and observe

    • After cleaning, wait several weeks before replacing parts
    • Monitor whether new corrosion appears
    • If corrosion stops, the anions may have reached balance

Not sure if your material is safe? Submit a ticket with the material’s MSDS attached. Our team will help you determine if it’s safe to process.